Diffusion-controlled chronoamperometry at a disk electrode.

نویسندگان

  • Peter J Mahon
  • Keith B Oldham
چکیده

An accurate formula exists for describing the decay of the current following the imposition of extreme concentration polarization on a disk electrode under diffusion-controlled conditions. It has been amply validated by diverse simulations and is presented here in a more compact form than hitherto. The formula finds application beyond the realm of potential-step chronoamperometry.

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عنوان ژورنال:
  • Analytical chemistry

دوره 77 18  شماره 

صفحات  -

تاریخ انتشار 2005